Product ID:SHELLZONE ANTIFREEZE
MSDS Date:11/13/1985
FSC:6850
NIIN:00-135-2878
MSDS Number: BLJRQ

SHELL OIL COMPANY

1 SHELL PLAZA
HOUSTON, TX 77001
US

Emergency Phone: 713-473-9461 (24 HOUR EMERGENCY)

Info Phone: 713-241-4819

Preparer: JOHN P. SEPESI

Cage: 54527

SHELL OIL COMPANY

2463 HOUSTON, TX 77210 US

Telephone: 800-231-6950

Cage: 54527

ETHYLENE GLYCOL (SARA III)

CAS: 107-21-1

RTECS: KW2975000

Fraction By Weight: 84-94%

OSHA PEL C 50 PPM

ACGIH TLV: C 50 PPM,VAPOR; 9192

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

DIETHYLENE GLYCOL

CAS: 111-46-6

RTECS: ID5950000

Fraction By Weight: 0-10%

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 2-4%

SALTS (INORGANIC AND ORGANIC)

Fraction By Weight: 2-4%

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES: MODERATELY TO SEVERELY
IRRITATION. SKIN: MILDLY IRRITATING AND SLIGHTLY TOXIC ON
PROLONGED OR REPEATED CONTACT. INHALATION: VAPORS ARE MILDLY TO
MARKEDLY IRRITATING TO THE LUNGS. INGESTION: M AY BE HARMFUL OR
FATAL. MAY PRODUCE CNSDEPRESSION AND KIDNEY DAMAGE. POSSIBLE LIVER
DAMAGE ALSO.
Effects of Overexposure:EARLY TO MODERATE CNS DEPRESSION MAY BE
EIDENCED BY GIDDINESS, HEADACHE, DIZZINESS AND NAUSEA. IN EXTREME
CASES, UNCONSCOIUSNESS AND DEATH. KIDNEY DAMAGE MAY BE EVIDENCED BY
CHANGES IN URINE OUTPUT, U RINE APPEARANCE OR EDEMA. LIVER DAMAGE
MAY BE EVIDENCED BY LOSS OF APPETITE. FAUNDICE AND SOMETIMES PAIN
IN UPPER ABDOM.
Medical Cond Aggravated by Exposure:SKIN, EYE AND RESPIRATORY
DISORDERS. ALSO KIDNEY AND LIVER FUNCTIONS.

First Aid:EYES: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
MIN. WHILE HOLDING EYELIDS OPEN. SKIN: FLUSH WITH WATER.
INHALATION: REMOVE VICTIM TO FRESH AIR AND PROVIDE OXYGEN IF
BREATHING IS DIFFIC ULT. GET MEDICAL ATTENTION. INGESTION:DO NOT
GIVE LIQUIDS IF VICTIM IS UNCONSCIOUS. OTHERWISE, GIVE NO MORE THAN
2 GLASSES OF WATER AND INDUCE VOMITING BY GIVING 30CC SYRUP OF
IPECAC.

Flash Point Method:SCC
Flash Point:246F,119C
Extinguishing Media:USE WATER FOG, ALCOHOL FOAM, DRY CHEMICAL OR CARBON
DIOXIDE.
Fire Fighting Procedures:MATERIAL WILL NOT VURN UNLESS PREHEATED. DO
NOT ENTER CONFINED FIRE SPACE WITH OUT FULL BUNKER GEAR, INCLUDING
A POSITIVE PRESSURE BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:COOL FIRE EXPOSED CONTAINERS WITH WATER.

Spill Release Procedures:WEAR RESPIRATOR AND PROTECTIVE CLOTHING. SHUT
OFF SOURCE OF LEAK IF SAFE TO DO SO. DIKE AND CONTAIN. REMOVE WITH
VACUUM TRUCKS OR PUMP TO STORAGE/SALVAGE VESSELS. SOAK UP RESIDUE
WITH AB ABSORBENT SUC H AS CLAY, SAND OR OTHER SUITABLE MATERIAL.
Neutralizing Agent:NONE

Handling and Storage Precautions:STORE IN A COOL, DRY PLACE WITH
ADEQUATE VENTILATION. KEEP AWAY FROM FLAMES AND HIGH TEMPERATURES.
Other Precautions:NONE

Respiratory Protection:USE A NIOSH-APPROVED RESPIRATOR TO PREVENT
OVEREXPOSURE.
Ventilation:USE LOCAL MECHANICAL VENTILATION.
Protective Gloves:NOT NORMALLY NECESSARY.
Eye Protection:NOT NORMALLY NECESSARY.
Other Protective Equipment:EYEWASH FOUNTAINS AND SAFETY SHOWER.
Work Hygienic Practices:WASH WITH SOAP AND WATER BEFORE EATING,
DRINKING, SMOKING OR USING TOILET FACILITIES. LAUNDER CONTAMINATED
CLOTHING.
Supplemental Safety and Health
NONE

HCC:N1
Boiling Pt:B.P. Text:330F,166C
Vapor Density:>1
Spec Gravity:1.1373
Evaporation Rate & Reference:<0.01 (N-BUTYL ACETATE=1)
Solubility in Water:COMPLETE
Appearance and Odor:BLUE-GREEN, SLIGHTLY VISCOUS LIQUID WITH A MILD
ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CARBON MONOXIDE AND UNIDENTIFIED
ORGANIC COMPOUNDS MAY BE FORMED DURING COMBUSTION.

Waste Disposal Methods:PLACE IN AN APPROPRIATE DISPOSAL FACILITY IN
COMPLIANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.